Autoionisation of super excited states in N2 to the N2+ B state
Författare
Summary, in English
Vibrationally resolved N2+ (B–X) (1–2) and (0–1) emission bands were recorded after photoexcitation of N2 in the 20–46 eV energy range. The branching ratio between these transitions reveals strong non-Franck–Condon effects. Ab initio calculations using a configuration interaction method based on Kohn–Sham orbitals indicate that the autoionisation of certain superexcited states is responsible for some structures present in the branching ratio curve.
Publiceringsår
2003
Språk
Engelska
Sidor
139-146
Publikation/Tidskrift/Serie
Chemical Physics Letters
Volym
372
Issue
1-2
Dokumenttyp
Artikel i tidskrift
Förlag
Elsevier
Ämne
- Electrical Engineering, Electronic Engineering, Information Engineering
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 0009-2614