Bicyclic diols and related derivatives as catalysts for the asymmetric diethylzinc addition to benzaldehyde

Summary, in English

Chiral bicyclic diols based on bicyclo[2.2.2]octane and bicyclo[2.2.1]heptane have been synthesized and their catalytic capacity in the asymmetric diethylzinc addition to benzaldehyde compared with those described for previously synthesized 2,6-bicyclo[2.2.2]octane-diols (BODOLs). The influence of the number of coordinating sites and the distance between them were studied. (C) 2008 Elsevier Ltd. All rights reserved.

• Författare: Cecilia Olsson; Annika Friberg; Torbjörn Frejd
• Avdelning/ar: Centrum för analys och syntes
• Publiceringsår: 2008
• Språk: Engelska
• Sidor: 1476-1483
• Publikation/Tidskrift/Serie: Tetrahedron: Asymmetry
• Volym: 19
• Issue: 12
• Länkar: http://dx.doi.org/10.1016/j.tetasy.2008.05.024
• Dokumenttyp: Artikel i tidskrift
• Förlag: Elsevier
• Ämne: Organic Chemistry
• Status: Published
• ISBN/ISSN/Övrigt: ISSN: 0957-4166