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Azinyl sulfides. LXXXI. 14-Phenyl-7-thiapyrano[2,3-c;6,5-c ']diquinoline-14-carbonitrile

Publiceringsår: 2005
Språk: Engelska
Sidor: O377-O379
Publikation/Tidskrift/Serie: Acta Crystallographica Section C - Crystal Structure Communications
Volym: 61
Nummer: Pt 6
Dokumenttyp: Artikel
Förlag: International Union of Crystallography


The molecules of the title compound, C26H15N3S, have a pentacyclic ring system which is almost planar, with the central ring in a flattened boat conformation. The folding angle between the two quinoline rings is 6.75 ( 7)degrees. The 14- phenyl substituent is in a quasi- axial conformation, while the 14-cyano substituent is in a quasi- equatorial conformation with respect to the thiopyran ring. The S center dot center dot center dot C - C-phenyl and S center dot center dot center dot C - C-CN angles are 116.8 ( 2) and 129.3 ( 2) degrees, respectively. The plane of the phenyl group is nearly coplanar with the plane bisecting the dihedral angle of the pentacyclic ring system.



  • Chemistry


  • ISSN: 0108-2701

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