Structure and Bonding of Ethylene Oxide on Si(100)
Författare
Summary, in English
The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.
Avdelning/ar
Publiceringsår
2009
Språk
Engelska
Sidor
16077-16082
Publikation/Tidskrift/Serie
Journal of Physical Chemistry C
Volym
113
Issue
36
Dokumenttyp
Artikel i tidskrift
Förlag
The American Chemical Society (ACS)
Ämne
- Physical Sciences
- Natural Sciences
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 1932-7447