Building, characterising and catalytic activity testing of Co-C-protected amino acid complexes covalently grafted onto chloropropylated silica gel
Författare
Summary, in English
Co-C-protected amino acid (C-protected L-histidine, L-tyrosine, L-cysteine and L-cystine) complexes were covalently grafted onto chloropropylated silica gel, and the materials thus obtained were structurally characterised by mid/far IR and X-ray absorption spectroscopies. The superoxide dismutase-like activities of the substances were determined via the Beauchamp-Fridovich test reaction. It was found that covalent grafting and the preparation of the anchored complexes were successful in most cases. The coordinating groups varied upon changing the conditions of the syntheses. All materials displayed catalytic activity, although catalytic activities differed widely. (C) 2014 Elsevier B.V. All rights reserved.
Avdelning/ar
Publiceringsår
2015
Språk
Engelska
Sidor
138-143
Publikation/Tidskrift/Serie
Journal of Molecular Structure
Volym
1090
Länkar
Dokumenttyp
Artikel i tidskrift
Förlag
Elsevier
Ämne
- Natural Sciences
- Physical Sciences
Nyckelord
- Co(II) amino acid complexes
- Covalent grafting
- FT-IR spectroscopy
- X-ray absorption spectroscopy
- Superoxide dismutase activity
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 0022-2860