Bis{μ-cis-1,3-bis-[(di-tert-butyl-phosphan-yl)-oxy]cyclo-hexane-κ(2) P:P'}bis-[carbonylnickel(0)] including an unknown solvent molecule.

Summary, in English

The title compound, [Ni2(C22H46P2O2)2(CO)2], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal-planar geometry. The cyclo-hexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific inter-molecular inter-actions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. Its formula mass and unit-cell characteristics were not taken into account during refinement.

• Författare: Klara Jonasson; Ola Wendt
• Avdelning/ar: Centrum för analys och syntes
• Publiceringsår: 2014
• Språk: Engelska
• Sidor: 176-177
• Publikation/Tidskrift/Serie: Acta Crystallographica Section E: Structure Reports Online
• Volym: 70
• Issue: Pt 5
• Länkar: http://dx.doi.org/10.1107/S1600536814007818
• Dokumenttyp: Artikel i tidskrift
• Förlag: International Union of Crystallography
• Ämne: Chemical Sciences
• Status: Published
• ISBN/ISSN/Övrigt: ISSN: 1600-5368