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Deactivation of Pt/Wire-Mesh and Vanadia/Monolith Catalysts Applied in Selective Catalytic Reduction of NOx in Flue Gas

In English

Författare

Summary, in English

In this study the deactivation of Pt/wire mesh and vanadia/monolith catalysts by aerosol particles of some inorganic salts (K2SO4, KCl and ZnCl2) with high or low melting points has been investigated. The aerosol particles may either diffuse within the matrix of the catalysts and block the mezzo and micro pores, or deposit on the outer surface of the catalysts and form a porous layer causing a mass transfer resistance that ultimately deactivates the catalysts. It has been observed that in both Pt/wire mesh and vanadia/monolith catalysts the deactivation effect of ZnCl2 was more pronouced compared to other salts. As an example, after 31 hours of exposure to ZnCl2, 10% of the catalysts activities was lost. This may be related to the ZnCl2 lower melting point in comparison with other poisons. These results are in agreement with the previous findings for deactivation of wire-mesh catalysts used for oxidation of volatile organic compounds (VOC) and CO by exposing the catalysts to the aerosols generated from inorganic salts.

Publiceringsår

2007

Språk

Engelska

Sidor

583-587

Publikation/Tidskrift/Serie

Korean Journal of Chemical Engineering

Volym

24

Issue

4

Dokumenttyp

Artikel i tidskrift

Förlag

Springer

Ämne

  • Production Engineering, Human Work Science and Ergonomics

Nyckelord

  • SCR
  • pt/wire mesh
  • vanadia/moolith
  • aerosol
  • deactivation
  • sub-micron particles

Status

Published

ISBN/ISSN/Övrigt

  • ISSN: 0256-1115