High-pressure Raman and infrared spectroscopic studies of ZrP2O7
Författare
Summary, in English
High-pressure Raman and mid-infrared spectroscopic studies were carried out on ZrP2O7 to 23.2 and 13 GPa respectively. In the pressure range 0.7-4.3 GPa the lattice mode at 248 cm(-1) disappears, new modes appear around 380 and 1111 cm(-1) and the strong symmetric stretching mode at 476 cm(-1) softens, possibly indicating a subtle phase transition. Above 8 GPa all the modes broaden, and all of the Raman modes disappear beyond 18 GPa. On decompression from the highest pressure, 23.2, to 0 GPa all of the modes reappear but with larger full width at half maximum. Lattice dynamics of the high temperature phase of ZrP2O7 were studied using first principles method and compared with experimental values. (C) 2009 Elsevier Ltd. All rights reserved.
Avdelning/ar
Publiceringsår
2010
Språk
Engelska
Sidor
235-239
Publikation/Tidskrift/Serie
Solid State Communications
Volym
150
Issue
5-6
Dokumenttyp
Artikel i tidskrift
Förlag
Pergamon Press Ltd.
Ämne
- Physical Sciences
- Natural Sciences
Nyckelord
- reflection
- Light absorption and
- high pressure
- Strain
- Inelastic light scattering
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 1879-2766