Water Tetramer, Pentamer, and Hexamer in Inert Matrices
Författare
Summary, in English
The infrared spectrum of water, isolated in inert matrices, has been studied in the interval from 60 to 4000 cm(-1). Experiments with partially deuterated water combined with DFT (density functional theory) calculations have been used to investigate the structure of matrix-isolated water tetramer. A few, strong intermolecular fundamentals of the water tetramer have been observed. Mid-infrared bands due to deuterated pentamers and hexamers have been observed and are used to discuss the assignments of these water clusters.
Avdelning/ar
Publiceringsår
2012
Språk
Engelska
Sidor
4842-4850
Publikation/Tidskrift/Serie
The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
Volym
116
Issue
20
Dokumenttyp
Artikel i tidskrift
Förlag
The American Chemical Society (ACS)
Ämne
- Atom and Molecular Physics and Optics
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 1520-5215