Javascript verkar inte påslaget? - Vissa delar av Lunds universitets webbplats fungerar inte optimalt utan javascript, kontrollera din webbläsares inställningar.
Du är här

Ligand Identification in Titanium Complexes Using X-ray Valence-to-Core Emission Spectroscopy

  • Janine C. Swarbrick
  • Yaroslav Kvashnin
  • Karina Schulte
  • Kalaivani Seenivasan
  • Carlo Lamberti
  • Pieter Glatzel
Publiceringsår: 2010
Språk: Engelska
Sidor: 8323-8332
Publikation/Tidskrift/Serie: Inorganic Chemistry
Volym: 49
Nummer: 18
Dokumenttyp: Artikel i tidskrift
Förlag: The American Chemical Society


The identification of ligands in metalloorganic complexes is crucial for understanding many important biological and chemical systems. Nonresonant K beta valence-to-core X-ray emission spectroscopy (XES) has been demonstrated as a ligand identification technique which is complementary to other spectroscopies, such as X-ray absorption. In this study we show the K beta valence-to-core XES alongside the Ti K-edge X-ray absorption near edge structure spectra for a series of chemically relevant low-symmetry Ti organometallic complexes. The spectra are modeled using density functional theory calculations. XES spectra are analyzed in terms of the molecular orbitals probed, in order to understand the effects of bond length, bond nature, orbital hybridization, and molecular symmetry on the observed spectral features.


  • Physical Sciences
  • Natural Sciences


  • ISSN: 1520-510X

Box 117, 221 00 LUND
Telefon 046-222 00 00 (växel)
Telefax 046-222 47 20
lu [at] lu [dot] se

Fakturaadress: Box 188, 221 00 LUND
Organisationsnummer: 202100-3211
Om webbplatsen