Azinyl sulfides. LXXXI. 14-Phenyl-7-thiapyrano[2,3-c;6,5-c ']diquinoline-14-carbonitrile

Summary, in English

The molecules of the title compound, C26H15N3S, have a pentacyclic ring system which is almost planar, with the central ring in a flattened boat conformation. The folding angle between the two quinoline rings is 6.75 ( 7)degrees. The 14- phenyl substituent is in a quasi- axial conformation, while the 14-cyano substituent is in a quasi- equatorial conformation with respect to the thiopyran ring. The S center dot center dot center dot C - C-phenyl and S center dot center dot center dot C - C-CN angles are 116.8 ( 2) and 129.3 ( 2) degrees, respectively. The plane of the phenyl group is nearly coplanar with the plane bisecting the dihedral angle of the pentacyclic ring system.

• Författare: Céline Besnard; C Kloc; Theo Siegrist; Christer Svensson; K Pluta
• Avdelning/ar: Centrum för analys och syntes; MAX IV-laboratoriet
• Publiceringsår: 2005
• Språk: Engelska
• Sidor: 377-379
• Publikation/Tidskrift/Serie: Acta Crystallographica. Section C: Crystal Structure Communications
• Volym: 61
• Issue: Pt 6
• Länkar: http://dx.doi.org/10.1107/S0108270105009832
• Dokumenttyp: Artikel i tidskrift
• Förlag: International Union of Crystallography
• Ämne: Chemical Sciences; Physical Sciences; Natural Sciences
• Status: Published
• ISBN/ISSN/Övrigt: ISSN: 0108-2701