Neutral fragmentation of super excited oxygen molecules
Författare
Summary, in English
The mechanisms of neutral dissociation of oxygen molecules in the excitation energy range 15–25 eV have been studied in a dispersed fluorescence experiment. By detecting the fluorescence from excited oxygen atoms, we find that neutral superexcited O2 states below 20 eV dissociate into O(g.s.)+O(3s,3p). At higher excitation energies (hν=20–25 eV) the curve-crossing interactions following excitations to members of the Rydberg c 4Σu- series also yield atoms in Rydberg states (nl,n>~4). The experimental data are analyzed on the ground of many-body perturbation theory, calculations which indicate the structure of the predissociating states converging to the experimentally observed ones.
Publiceringsår
2000
Språk
Engelska
Publikation/Tidskrift/Serie
Physical Review A (Atomic, Molecular and Optical Physics)
Volym
61
Issue
3
Dokumenttyp
Artikel i tidskrift
Förlag
American Physical Society
Ämne
- Electrical Engineering, Electronic Engineering, Information Engineering
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 1050-2947