Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands

Summary, in English

Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.

• Författare: Athimoolam Arunachalampillai; Magnus Johnson; Ola Wendt
• Avdelning/ar: Centrum för analys och syntes
• Publiceringsår: 2008
• Språk: Engelska
• Sidor: 4541-4543
• Publikation/Tidskrift/Serie: Organometallics
• Volym: 27
• Issue: 17
• Länkar: http://dx.doi.org/10.1021/om800444g
• Dokumenttyp: Artikel i tidskrift
• Förlag: The American Chemical Society (ACS)
• Ämne: Organic Chemistry
• Status: Published
• ISBN/ISSN/Övrigt: ISSN: 1520-6041