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Synthesis, spectroscopic characterization and catalytic activity of platinum(II) carbene complexes

In English

Författare

  • Ekaterina Bolbat
  • Karina Suarez-Alcantara
  • Sophie E. Canton
  • Ola F. Wendt

Summary, in English

A novel platinum complex with 1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidenyl ligand has been synthesized and characterized on the basis of elemental analysis, MS, 1H and 13C NMR spectroscopy, X-ray Absorption Spectroscopy and single crystal X-ray diffraction studies. The XRD determination of the complex (monoclinic, C2/c) revealed a structure in which the platinum (II) centre coordinates two chlorides, a carbon atom of the N-heterocyclic carbene (NHC) and is stabilized by coordinating the nitrogen atom of a 3-chloropyridine molecule, forming an over-all square planar geometry. By prolonging the time of the reaction, it was possible to obtain the trans-dichloridobis(3-chloropyridine) platinum(II) complex under the same reaction conditions. The electronic and molecular properties of both complexes were investigated and compared by means of Near Edge X-ray Absorption Fine Structure spectroscopy (NEXAFS), supported by numerical simulations. The platinum carbene complex obtained was tested in a series of C-H activation and hydrosilylation reactions.

Publiceringsår

2016-04-24

Språk

Engelska

Sidor

129-133

Publikation/Tidskrift/Serie

Inorganica Chimica Acta

Volym

445

Dokumenttyp

Artikel i tidskrift

Förlag

Elsevier

Ämne

  • Inorganic Chemistry

Nyckelord

  • EXAFS
  • Hydrosilylation
  • NHC carbene complexes
  • Platinum
  • XRD

Status

Published

ISBN/ISSN/Övrigt

  • ISSN: 0020-1693