Chirality, a never-ending source of confusion
Författare
Summary, in English
In this Discussion a few points of confusion concerning chirality are clarified. The term chirodescriptive is proposed for such space groups that lack inversion centres, reflection planes, glide planes or rotary-inversion axes and thus can contain enantiopure, chiral objects. It is pointed out that chiral compounds can (and often do) crystallise in non-chirodescriptive space group when they occur as racemates and in such cases there is no incompatibility between chirality and mirror planes or centres of inversions. We also propose the term raceomorphism to describe the relationship between a conglomerate and a collection of racemic crystals of the same compound.
Avdelning/ar
Publiceringsår
2009
Språk
Engelska
Sidor
607-608
Publikation/Tidskrift/Serie
Zeitschrift für Kristallographie
Volym
224
Issue
12
Dokumenttyp
Artikel i tidskrift
Förlag
Oldenbourg Verlag
Ämne
- Organic Chemistry
Nyckelord
- Raceomorphism
- Enantiomorphism
- Chiral
- Chirodescriptive
- Chirogenic
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 0044-2968