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Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases

Författare:
Publiceringsår: 2010
Språk: Engelska
Sidor: 334-337
Publikation/Tidskrift/Serie: Inorganic Chemistry Communications
Volym: 13
Nummer: 3
Dokumenttyp: Artikel
Förlag: Elsevier Science BV

Sammanfattning

The heterodinuclear complexes FeZn(L)(CH3CO2)(2)(+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved

Disputation

Nyckelord

  • Chemistry
  • Transesterification
  • Model complexes
  • phosphatase
  • Purple acid
  • Dinuclear
  • Bioinorganic chemistry
  • Heterodinuclear
  • Zinc
  • Iron
  • HPNP

Övrigt

Published
Yes
  • ISSN: 1387-7003

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