Dual graphs realized in the compounds di-mu(3)-4-mercaptopyridine catena-di-mu(2)-iodo-di-mu(3)-iodo-mu(4)-iodo penta copper(I) and di-mu(3)-4-mercaptopyridine-di-catena-iodo-di-mu(3)-iodo tri copper(I)

Summary, in English

Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group 141/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is non-bonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide. (C) 2010 Elsevier Inc. All rights reserved.

• Författare: Ehsan Jalilian; Sven Lidin
• Avdelning/ar: Centrum för analys och syntes
• Publiceringsår: 2010
• Språk: Engelska
• Sidor: 2656-2661
• Publikation/Tidskrift/Serie: Journal of Solid State Chemistry
• Volym: 183
• Issue: 11
• Länkar: http://dx.doi.org/10.1016/j.jssc.2010.09.009
• Dokumenttyp: Artikel i tidskrift
• Förlag: Elsevier
• Ämne: Chemical Sciences
• Nyckelord: Structure; Copper(I); Iodide; Cluster
• Status: Published
• ISBN/ISSN/Övrigt: ISSN: 0022-4596