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Water Tetramer, Pentamer, and Hexamer in Inert Matrices

Publiceringsår: 2012
Språk: Engelska
Sidor: 4842-4850
Publikation/Tidskrift/Serie: Journal of Physical Chemistry A
Volym: 116
Nummer: 20
Dokumenttyp: Artikel
Förlag: American Chemical Society


The infrared spectrum of water, isolated in inert matrices, has been studied in the interval from 60 to 4000 cm(-1). Experiments with partially deuterated water combined with DFT (density functional theory) calculations have been used to investigate the structure of matrix-isolated water tetramer. A few, strong intermolecular fundamentals of the water tetramer have been observed. Mid-infrared bands due to deuterated pentamers and hexamers have been observed and are used to discuss the assignments of these water clusters.



  • Atom and Molecular Physics and Optics


  • ISSN: 1089-5639

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