Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction

Summary, in English

The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.

• Författare: Emelie Bjurling; Ulf Berg; CM Andersson
• Avdelning/ar: Centrum för analys och syntes
• Publiceringsår: 2002
• Språk: Engelska
• Sidor: 1583-1590
• Publikation/Tidskrift/Serie: Organometallics
• Volym: 21
• Issue: 8
• Länkar: http://dx.doi.org/10.1021/om011016g
• Dokumenttyp: Artikel i tidskrift
• Förlag: The American Chemical Society (ACS)
• Ämne: Organic Chemistry
• Status: Published
• ISBN/ISSN/Övrigt: ISSN: 1520-6041