The coupling between translation and rotation for monomeric water in noble gas matrices.
Författare
Summary, in English
The rotation of water in noble gas matrices has been studied. It is shown that the rotation-translation coupling model of Friedmann and Kimel predicts rotation line spacings, which are close to the experimental observations for H2O, D2O, and HDO, when gas phase rotation constants are used. The model gives intensity estimates in reasonable agreement with the observations for the local oscillator bands, which accompany the rotation spectrum. It also predicts the intensity variations in the bending region of H2O between neon, argon, and krypton matrices.
Avdelning/ar
Publiceringsår
2013
Språk
Engelska
Publikation/Tidskrift/Serie
Journal of Chemical Physics
Volym
138
Issue
24
Dokumenttyp
Artikel i tidskrift
Förlag
American Institute of Physics (AIP)
Ämne
- Physical Sciences
- Atom and Molecular Physics and Optics
- Natural Sciences
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 0021-9606