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Effect of impurities on structural and electrochemical properties of the Ni-YSZ interface.

In English

Författare

Summary, in English

The changes in interface structure and chemical composition of a 99.995% pure nickel/yttria-stabilised zirconia (YSZ) interface were examined after heat treatment at 1000 °C in 97% H2/3% H2O with and without polarisation. Impedance spectroscopy was used for electrochemical characterisation. The results were compared to earlier investigations of a less pure nickel/YSZ interface.



The pure interface developed different structures depending on whether or not the samples were polarised. Despite the purity of the nickel, impurities were found in the interfacial region. The pure electrodes/interfaces showed area specific polarisation resistances 10 times lower than the impure interfaces.

Publiceringsår

2003

Språk

Engelska

Sidor

27-37

Publikation/Tidskrift/Serie

Solid State Ionics

Volym

160

Issue

1-2

Dokumenttyp

Artikel i tidskrift

Förlag

Elsevier

Ämne

  • Chemical Sciences

Nyckelord

  • Foreign phases
  • Polarisation resistance
  • Ni–YSZ interface
  • SOFC
  • Anode

Status

Published

ISBN/ISSN/Övrigt

  • ISSN: 0167-2738