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Molecular nature of resonant x-ray scattering in solid LiNO3

In English

Författare

Summary, in English

Resonant x-ray emission spectroscopy has been applied to study radiative decay processes following the N 1s near-edge excitations in solid LiNO3. It has been shown that the origin of both nonresonant and resonant spectra are essentially molecular, their shape being primarily determined by the electron transitions between molecular orbitals of the quasiisolated NO3- anion. A strong low-energy sideband observed in the recombination spectrum following the N 1s(-1)pi(*) excitation is attributed to the effect of dynamical x-ray emission accompanying the D-3h-->C-3v distortion of the core-excited NO3- species.

Publiceringsår

2004

Språk

Engelska

Publikation/Tidskrift/Serie

Physical Review B (Condensed Matter and Materials Physics)

Volym

69

Issue

11

Dokumenttyp

Artikel i tidskrift

Förlag

American Physical Society

Ämne

  • Natural Sciences
  • Physical Sciences

Status

Published

ISBN/ISSN/Övrigt

  • ISSN: 1098-0121