Intramolecular vibronic dynamics in molecular solids: C60
Författare
Summary, in English
Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.
Avdelning/ar
Publiceringsår
2005
Språk
Engelska
Publikation/Tidskrift/Serie
Physical Review B (Condensed Matter and Materials Physics)
Volym
72
Issue
20
Dokumenttyp
Artikel i tidskrift
Förlag
American Physical Society
Ämne
- Physical Sciences
- Atom and Molecular Physics and Optics
- Natural Sciences
Status
Published
ISBN/ISSN/Övrigt
- ISSN: 1098-0121