Webbläsaren som du använder stöds inte av denna webbplats. Alla versioner av Internet Explorer stöds inte längre, av oss eller Microsoft (läs mer här: * https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Var god och använd en modern webbläsare för att ta del av denna webbplats, som t.ex. nyaste versioner av Edge, Chrome, Firefox eller Safari osv.

Fourier-based approach to overcome anomalies in high-resolution spectra of vibrational CARS measurements of gases

In English

Författare

Summary, in English

In this work, we report on an unconventional experimental procedure useful for thermometric measurements on the basis of high-resolution vibrational coherent anti-Stokes Raman scattering (CARS) generated using conventional lasers. The high spectral dispersion of 0.02 cm(-1)/pixel is achieved by means of some specific spectral arrangements (single-mode pump laser and diffraction grating providing spectra at the sixth order) and is further strengthened by the use of a relay lens system mounted before the charge-coupled device camera. Surprisingly, at the high spectral dispersion of our measurements, a significant and persistent thermometric inaccuracy is observed. The effect arises from an inevitable spectral modulation of defined frequency hidden in the main CARS signal of the gas under study, and to secure a good thermometric evaluation, we describe a Fourier approach that is experimentally demonstrated for the typical nitrogen CARS spectrum measured at room temperature. Copyright (C) 2014 John Wiley & Sons, Ltd.

Publiceringsår

2014

Språk

Engelska

Sidor

489-494

Publikation/Tidskrift/Serie

Journal of Raman Spectroscopy

Volym

45

Issue

7

Dokumenttyp

Artikel i tidskrift

Förlag

John Wiley & Sons Inc.

Ämne

  • Atom and Molecular Physics and Optics

Nyckelord

  • coherent anti-Stokes Raman scattering
  • laser spectroscopy
  • spectroscopic
  • techniques

Status

Published

ISBN/ISSN/Övrigt

  • ISSN: 1097-4555