Cyclometallated phenyl-pyridine palladium species. Monomeric complex formation with potentially bridging ligands

Summary, in English

The cyclometallated dinuclear (2-phenyl-pyridine) palladium acetate and chloride [{PdCl(phpy)}(2)] and [{PdOAc(phpy)}(2)] were reacted with potentially bridging N- and S-donor ligands. The N,N-ligands bind with only one nitrogen and form monomeric products. The S,S-ligand binds in a chelate mode, also forming a monomeric complex. 3,3-Dimethyl glutarate, on the other hand, binds in a bridging mode. An X-ray structure of the complex with naphthyridine is presented. (C) 2016 Elsevier B.V. All rights reserved.

• Författare: Mikhail Kondrashov; Roman Gritcenko; André Fleckhaus; Ola Wendt
• Avdelning/ar: Centrum för analys och syntes
• Publiceringsår: 2016
• Språk: Engelska
• Sidor: 136-140
• Publikation/Tidskrift/Serie: Inorganica Chimica Acta
• Volym: 443
• Länkar: http://dx.doi.org/10.1016/j.ica.2015.12.032
• Dokumenttyp: Artikel i tidskrift
• Förlag: Elsevier
• Ämne: Inorganic Chemistry
• Nyckelord: Palladium; Bidentate ligands; Bridging ligands; C-H activation
• Status: Published
• ISBN/ISSN/Övrigt: ISSN: 0020-1693