{mu-2-[1-(N,N-Dimethylamino)ethyl]ferrocene-1,1 '-diylbis(diphenylphosphine)-kappa P-2 : P '}-bis[chlorogold(I)]

Summary, in English

The structure of the title compound, [ Au2Fe( C21H23NP)( C17H14P) Cl-2], displays the pseudo-linear [ P - Au - Cl = 175.4 ( 1) and 174.0 ( 1) degrees] two-coordinate geometry usually observed in gold( I) complexes. The Au - P bond distances are 2.237 ( 2) and 2.224 ( 2) angstrom and the Au - Cl distances are 2.271 ( 3) and 2.278 ( 2) angstrom. The bis( diphenylphosphino)ferrocenyl ligand links the gold metal centres in a bidentate fashion via the ferrocene group, thus leading to a binuclear gold system.

• Författare: Z A Sam; Åke Oskarsson; Sofi Elmroth; Andreas Roodt
• Avdelning/ar: Centrum för analys och syntes; Biokemi och Strukturbiologi
• Publiceringsår: 2005
• Språk: Engelska
• Sidor: 2090-2092
• Publikation/Tidskrift/Serie: Acta Crystallographica Section E: Structure Reports Online
• Volym: 61
• Issue: 10
• Länkar: http://dx.doi.org/10.1107/S1600536805029582
• Dokumenttyp: Artikel i tidskrift
• Förlag: International Union of Crystallography
• Ämne: Organic Chemistry; Biological Sciences
• Status: Published
• ISBN/ISSN/Övrigt: ISSN: 1600-5368