Webbläsaren som du använder stöds inte av denna webbplats. Alla versioner av Internet Explorer stöds inte längre, av oss eller Microsoft (läs mer här: * https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Var god och använd en modern webbläsare för att ta del av denna webbplats, som t.ex. nyaste versioner av Edge, Chrome, Firefox eller Safari osv.

Time-domain measurements of S-branch N-2-N-2 Raman linewidths using picosecond pure rotational coherent anti-Stokes Raman spectroscopy

In English

Författare

  • C. J. Kliewer
  • Alexis Bohlin
  • Emil Nordström
  • B. D. Patterson
  • Per-Erik Bengtsson
  • T. B. Settersten

Summary, in English

Time-resolved dual-broadband picosecond pure rotational CARS has been applied to measure self-broadened S-branch N-2-N-2 Raman linewidths in the temperature range 294-1466 K. The coherence decays were detected directly in the time domain by following the J-dependent CARS signal decay as a function of probe delay. The rotational Raman N-2-N-2 linewidths were derived from these time-dependent decays and evaluated for thermometric accuracy. Comparisons were made to the energy-corrected sudden (ECS) and modified exponential gap (MEG) dynamical scaling laws, and the results were used to quantify the sensitivity of nanosecond rotational CARS thermometry to the linewidth model employed. The uncertainty based on the linewidth model used in pure N-2 was found to be 2 %. The merits and limitations of this rapid method for the determination of accurate Raman linewidths are discussed.

Publiceringsår

2012

Språk

Engelska

Sidor

419-426

Publikation/Tidskrift/Serie

Applied Physics B

Volym

108

Issue

2

Dokumenttyp

Artikel i tidskrift

Förlag

Springer

Ämne

  • Atom and Molecular Physics and Optics

Status

Published

ISBN/ISSN/Övrigt

  • ISSN: 0946-2171