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Chiral recognition of Nα-protected amino acids and derivatives in molecularly imprinted polymers.

In English

Författare

Summary, in English

Highly crosslinked synthetic polymers, selective for various Nα-protected amino acids and derivatives, were prepared by non-covalent molecular imprinting. Methacrylic acid and ethylene glycol dimethacrylate were copolymerized in the presence of the print molecules, which were subsequently extracted from the polymers. The recognition of the polymers for the print molecules and molecules of similar structures was investigated by using the polymers as stationary phases in HPLC. The functional groups of the print molecules interact via hydrogen bonds with the positioned carboxyls of the polymer. It was shown that the Nα-protecting group, the Cα-protecting group and the amino acid side chain are also recognized by the binding sites in the polymer.

Publiceringsår

1994

Språk

Engelska

Sidor

603-606

Publikation/Tidskrift/Serie

International Journal of Peptide and Protein Research

Volym

44

Issue

6

Dokumenttyp

Artikel i tidskrift

Förlag

Munksgaard Forlag

Ämne

  • Biochemistry and Molecular Biology

Status

Published

Forskningsgrupp

  • Nanomedicine and Biomaterials

ISBN/ISSN/Övrigt

  • ISSN: 0367-8377