Webbläsaren som du använder stöds inte av denna webbplats. Alla versioner av Internet Explorer stöds inte längre, av oss eller Microsoft (läs mer här: * https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Var god och använd en modern webbläsare för att ta del av denna webbplats, som t.ex. nyaste versioner av Edge, Chrome, Firefox eller Safari osv.

Crystalline Iron Oxohalide Nanotube Pea Pods

In English

Författare

Summary, in English

Compounds Fe7Sb3(PO4)3O6Cl3 and Fe7Sb3(PO4)3O6Br3 are the first iron phosphates containing SbIII. They were synthesized by chemical vapor transport reactions, and their crystal structures were characterized by single-crystal X-ray diffraction. The compounds are isostructural and crystallize in the orthorhombic space group Pnma. Tubular Fe7(PO4)3O6X3 units (X = Cl, Br) are linked by SbO4 groups to build up a framework. The tubular units consist of an outer part made up of [FeO5X] octahedra where the Fe atoms are arranged to resemble a nanotube. Inside the tubes there are phosphate groups, and at the very center there is a chain of face-sharing [FeO6] octahedra.

Publiceringsår

2012

Språk

Engelska

Sidor

3971-3974

Publikation/Tidskrift/Serie

European Journal of Inorganic Chemistry

Issue

25

Dokumenttyp

Artikel i tidskrift

Förlag

John Wiley & Sons Inc.

Ämne

  • Chemical Sciences

Nyckelord

  • Oxohalides
  • Structure elucidation
  • Nanostructures
  • Iron
  • Antimony

Status

Published

ISBN/ISSN/Övrigt

  • ISSN: 1099-0682